Sure!!
I washed away all the old paint by using grafitti-remover-liquid, after that I sanded the rims with granulation 600, sprayed 4 laxere primer on, sanded again, sprayed 4 layers black shiny paint on, pin striped them, sprayed 4 layers 2K-clearcoat on and ready!!!
During the drying times I polished and painted the old center caps!!